Optical rotation of the molybdate complex of dextro-isocitric acid.

نویسندگان

  • L V EGGLESTON
  • H A KREBS
چکیده

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منابع مشابه

The effect of citrate on the rotation of the molybdate complexes of malate, citramalate and isocitrate.

Extracts of liver and muscle convert citric acid into laevo-rotatory isocitric acid [Martius, 1938]. As the rotation of isocitric acid, like that ofother ac-hydroxy acids, is much increased by (NH4)2MoO4*, the polarimeter can be used to measure low concentrations of isocitric acid in tissue extracts [Martius, 1938; Jacobsohn, 1940]. On applying this method to plant extracts we met with an unexp...

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A Theoretical Study of the Stability and Dielectric Constants of Molybdate-Phosphonic Acid Complex

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Basis Set Effects in Density Functional Calculations and BSSEcorrected on the Molybdate-Phosphonic acid Complex

In this research, this possibility was investigated the relative stablilty geometry and bindingenergies of the hydrogen bonds of Molybdate-Phosphonic Acid (MPA) complex in gas phase onthe basis of result of ab initio and DFT calculations. Three DFT methods have been applied forcalculations are B3LYP, BP86 and B3PW91 that have been studied in two series of basis sets:D95** and 6-31+G(d,p) for hy...

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Rationalizing the Strength of Hydrogen-Bonded of Molybdate-Phosphonic acid Complex (1:2): Density Functional Theory Studies

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Cooh Cooh Cooh Cooh

The natural occurrence of optically active isocitric acid was first demonstrated by Nelson' and Bruce(2) in blackberry fruits, and a somewhat large accumulation of the acid was found by Pucher et al. 3~ in Bryophyllum leaf tissue. This acid has also been recognized as a member of the tri-carboxylic acid cycle in many animals, plants and microorganisms. All isocitric acid, found before in nature...

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عنوان ژورنال:
  • The Biochemical journal

دوره 45 5  شماره 

صفحات  -

تاریخ انتشار 1949